Electrical Properties of Thin Organic Films

作者：Arthur T. Bradley, John P. Hammes · 发表于：Journal of The Electrochemical Society · 年份：1963 · DOI：10.1149/1.2425663 · 被引用次数：145 · 研究领域：Conducting polymers and applications、Fuel Cells and Related Materials、Analytical Chemistry and Sensors

Thin organic polymer film specimens were prepared for electrical conductivity measurements by the glow discharge polymerization process. The experimental procedure for film preparation is described in detail. Data on film properties and deposition efficiencies (g/kwhr) are presented for their possible bearing on the polymerization mechanisms. Dark conductivities (σ) were measured over the temperature range 75°–275°C. Plots of generally gave straight lines above about 125° with slopes characteristic of the chemical composition of the polymer film. Conductivities at 150°C ranged from 10 −17 mho/cm (films rich in halogen) to 10 −13 mho/cm (ferrocene, tetracyanoethylene). A possible relationship between structure and conductivity is discussed.