Theory and experimental evidence of electroconvection around electrochemical deposits

作者：Vincent Fleury, Jean Noël Chazalviel, Michel Rosso · 发表于：Physical Review Letters · 年份：1992 · DOI：10.1103/physrevlett.68.2492 · 被引用次数：183 · 研究领域：Theoretical and Computational Physics、Electrochemical Analysis and Applications、Electrodeposition and Electroless Coatings

We propose a model for the motion of the fluid flow, for the electric field, and for the concentration map around the branches during electrodeposition of ramified metal clusters in two-dimensional cells. This model accounts for the observed distribution of ions in the solution around the metal tips.