Heterobimetallic complexes viaη 1 -Ph 2 PCH 2 PPH 2 complexes of platinum or palladium dicyanides

作者：Paul G. Pringle, Bernard L. Shaw · 发表于：Journal of the Chemical Society Chemical Communications · 年份：1982 · DOI：10.1039/c39820000956 · 被引用次数：21 · 研究领域：Organometallic Complex Synthesis and Catalysis、Metal complexes synthesis and properties、Magnetism in coordination complexes

The cyanide ion is shown to be an excellent ligand for stabilising the fluxional η1-dppm complexes, trans-[M(CN)2(η1-dppm)2](M = Pt or Pd, dppm = Ph2PCH2PPh2), which can be used as key intermediated in the systematic synthesis of heterobimetallic (µ-dppm) complexes with silver, mercury, or rhodium.