Vibrational Excitation in Benzene by Electron Impact via Resonances: Selection Rules

作者：S. F. Wong, George J. Schulz · 发表于：Physical Review Letters · 年份：1975 · DOI：10.1103/physrevlett.35.1429 · 被引用次数：145 · 研究领域：Spectroscopy and Quantum Chemical Studies、Molecular Junctions and Nanostructures、Electrochemical Analysis and Applications

The vibrational excitation in the energy ranges of the lowest resonances in benzene has been measured and it is found that only few fundamental modes become excited. This selectivity of the excitation process can be understood in terms of selection rules which are based on symmetry considerations. The angular distribution of scattered electrons in the range of the lowest shape resonance (\ensuremath{\sim}1.2 eV) is consistent with an ${f}_{\ensuremath{\delta}}$ wave as the dominant partial wave.