Synthesis of Extremely Large Mesoporous Activated Carbon and Its Unique Adsorption for Giant Molecules

作者：Hisashi Tamai, Takuhiro Kakii, Yoshifumi Hirota, Tomio Kumamoto, Hajime Yasuda · 发表于：Chemistry of Materials · 年份：1996 · DOI：10.1021/cm950381t · 被引用次数：255 · 研究领域：Mesoporous Materials and Catalysis、Synthesis and properties of polymers、Polymer Nanocomposites and Properties

The steam invigoration of pitches (softening points 85 and 280 °C) homogenized with 1−3 wt % of organo rare-earth metal complexes such as Ln(C 5 H 5 ) 3 or Ln(acac) (Ln = Y, Yb) at 930 °C provided activated carbons with an extremely high mesopore ratio, >70%. The resulted activated carbon selectively adsorbs giant molecules such as vitamin B 12, blue acid 90 dye, dextran, nystatin, and humic acid, reflecting their large mesopore volumes. To understand what kind of carbon skeleton in pitch is suited for generation of high mesopore ratio, the steam invigoration of a series of condensed polynuclear aromatics (COPNA) resins prepared from naphthalene, anthracene, phenanthrene, pyrene, or perylene and p -xylene-α,α‘-diol were conducted in the presence of rare-earth metal complexes. As a result, COPNA resins containing phenanthrene, perylene, and pyrene generated large mesopore volume.