New Reactions of IBX: Oxidation of Nitrogen‐ and Sulfur‐Containing Substrates To Afford Useful Synthetic Intermediates

作者：K. C. Nicolaou, Casey J. N. Mathison, Tamsyn Montagnon · 发表于：Angewandte Chemie International Edition · 年份：2003 · DOI：10.1002/anie.200352076 · 被引用次数：265 · 研究领域：Oxidative Organic Chemistry Reactions、Synthesis and Catalytic Reactions、Chemical Synthesis and Reactions

New reactions for the synthetic toolbox: 2-Iodoxybenzoic acid (IBX) was employed to access a diverse array of useful synthetic intermediates. Among other transformations, the developed chemistry converts amines into imines, dithianes into carbonyl groups, N-heterocycles into N-heteroaromatic compounds, and hydroxylamines into oximes in high yields.