Sidewall Functionalization of Carbon Nanotubes This work was supported by the European Union under the 5th Framework Research Training Network 1999, HPRNT 1999-00011 FUNCARS.
作者:Michael Holzinger, Otto Vostrowsky, Andreas Hirsch, Frank H. Hennrich, Manfred M. Kappes, Robert A Weiss, Frank Jellen · 发表于:Angewandte Chemie International Edition · 年份:2001 · DOI:10.1002/1521-3773(20011105)40:21<4002::aid-anie4002>3.0.co;2-8 · 被引用次数:616 · 研究领域:Molecular Junctions and Nanostructures、Chemical Reactions and Mechanisms、Carbon Nanotubes in Composites
The addition of nitrenes, nucleophilic carbenes, and radicals affords soluble, individual single-walled nanotubes (shown here is a carbene-functionalized adduct) by covalent sidewall functionalization. The characterization, a fundamental problem in nanotube chemistry, is simple to carry out.