Polyarylenes and poly(arylenevinylene)s, 4. Novel anthracene‐containing poly(arylenevinylene)s via poly‐Heck reaction

作者：Hans‐Peter Weitzel, Kläus Müllen · 发表于：Die Makromolekulare Chemie · 年份：1990 · DOI：10.1002/macp.1990.021911131 · 被引用次数：71 · 研究领域：Organic Electronics and Photovoltaics、Synthesis and Properties of Aromatic Compounds、Cyclization and Aryne Chemistry

Abstract Heck reactions with anthracene‐containing compounds are investigated. Some oligomeric model compounds as well as polymers were synthesized. The reason for the failure of 9,10‐divinylanthracene to undergo the Heck reaction are described. The solution of the synthetic problem was achieved by using the yet unknown 9,10‐bis(1,3‐butadienyl)anthracene.