Noncrystalline Structures of Ultrathin Unsupported Nanowires

作者：Oğuz Gülseren, Furio Ercolessi, Erio Tosatti · 发表于：Physical Review Letters · 年份：1998 · DOI：10.1103/physrevlett.80.3775 · 被引用次数：278 · 研究领域：nanoparticles nucleation surface interactions、Surface and Thin Film Phenomena、Microstructure and mechanical properties

Computer simulations suggest that ultrathin metal wires should develop exotic, noncrystalline stable atomic structures once their diameter decreases below a critical size of the order of a few atomic spacings. The new structures, whose details depend upon the material and the wire thickness, may be dominated by icosahedral packings. Helical, spiral-structured wires with multiatom pitches are also predicted. The phenomenon, analogous to the appearance of icosahedral and other noncrystalline shapes in small clusters, can be rationalized in terms of surface energy anisotropy and optimal packing.