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catena -Poly[[(acetato-κ O )(1,10-phenanthroline-κ 2 N , N ′)nickel(II)]-μ-acetato-κ 2 O : O ′]

作者:H. Zhong, X.-M. Yang, H.-L. Xie, C.-J. Luo · 发表于:Acta Crystallographica Section E Structure Reports Online · 年份:2007 · DOI:10.1107/s1600536807058540 · 被引用次数:1 · 研究领域:Crystallography and molecular interactions、Crystal structures of chemical compounds、Metal-Organic Frameworks: Synthesis and Applications

In the polymeric title complex, [Ni(C2H3O2)2(C12H8N2)]n, NiII ions are bridged by single syn–anti acetate ligands. Each Ni atom is five-coordinated by two 1,10-phenanthroline N atoms and three O atoms of acetate ligands in a distorted square-pyramidal coordination geometry. In the crystal structure, C—H⋯O hydrogen bonds result in the formation of a polymeric ribbon structure.